Time-resolved operando DRIFTS-MS was performed to elucidate the CO2 capture and conversion mechanisms of a NiRuNa/CeAl DFM in CO2 methanation, reverse water-gas shift, and dry reforming of methane. CO2 was captured mainly in the form of carbonyls and bidentate carbonates, and a spillover mechanism occurred to obtain the desired products.
Since climate change keeps escalating, it is imperativethat theincreasing CO2 emissions be combated. Over recent years,research efforts have been aiming for the design and optimizationof materials for CO2 capture and conversion to enable acircular economy. The uncertainties in the energy sector and the variationsin supply and demand place an additional burden on the commercializationand implementation…
The signal crosstalk and electromagnetic interference (EMI) problems direly need to be resolved in the rapid development of modern microwave communication technology for a better working frequency and transmission power of electronic systems. Where the new absorbing materials such as molybdenum disulfide (MoS2)/titania (TiO2)/Ti2CTx and MoS2/Ti2CTx composites could meet the requirement of «thin, strong, light…
Quantum mechanical fluctuations of the electromagnetic field in a vacuum between two close together objects result in an attractive force. Now, it has been experimentally shown that by exploiting a similar repulsive interaction, attraction between objects can be modulated simply by tuning temperature.
There are multiple factors that influence the catalyst performance in the reaction of formic acid dehydrogena-tion: the nature of catalyst and/or support, the used solvent and reaction variables such as temperature, time, formic acid concentration, presence/absence of formates and pH of the solution. This work evaluates a series of important parameters like the influence of…
Icing has become a hot topic both in academia and in the industry given its implications in transport, wind turbines, photovoltaics, and telecommunications. Recently proposed de-icing solutions involving the propagation of acoustic waves (AWs) at suitable substrates may open the path for a sustainable alternative to standard de-icing or anti-icing procedures. Herein, the fundamental interactions…
Y3Al5O12 (YAG) is a widely used phosphor host. Its optical properties are controlled by chemical substitution at its YO8 or AlO6/AlO4 sublattices, with emission wavelengths defined by rare-earth and transition-metal dopants that have been explored extensively. Nonstoichiometric compositions Y3+xAl5-xO12 (x not equal 0) may offer a route to new emission wavelengths by distributing dopants over…
Reduction pre-treatment at different temperatures were performed over Mo/HZSM-5 system before methane dehydroaromatiztion reaction. We have shown the crucial effect of reduction temperature on the final catalytic performance. Outstanding improvement in the aromatics conversion has been attained. Thus, H-2 formation form methane cracking reaction seems to be hindered for pre-treated catalysts. As a consequence, the…
The Calcium-Looping (CaL) process, based on the multicyclic calcination-carbonation of CaCO3/CaO, is considered a promising Thermochemical Energy Storage (TCES) technology to be integrated into Concentrating Solar Power (CSP) plants. This work proposes a novel CaL integration that operates at low-pressure calcination under pure CO2 and a moderated temperature. Low-pressure calcination (0.01 bar) provides a suitable solution…
Optimization of Pt-promoted TiO2-based is key to promote the photocatalytic production of hydrogen using sacrificial alcohol molecules. Combination of doping and surface decoration of the mentioned base photoactive material is here exploited to maximize hydrogen yield. Using the quantum efficiency parameter, it is shown that the resulting composite system can boost activity up to 7.3…