Finite Size Effects on Light Propagation throughout Random Media: Relation between Optical Properties and Scattering Event Statistics

This work introduces a thorough analysis of light transport in thin optically disordered media. The diffusive properties of a turbid material are generally dictated by the transport mean free path, lt. For depths larger than this characteristic length, light propagation can be considered fully randomized. There is however a range of thicknesses for which light becomes…

Enhanced Stability of Perovskite Solar Cells Incorporating Dopant-Free Crystalline Spiro-OMeTAD Layers by Vacuum Sublimation

The main handicap still hindering the eventual exploitation of organometal halide perovskite-based solar cells is their poor stability under prolonged illumination, ambient conditions, and increased temperatures. This article shows for the first time the vacuum processing of the most widely used solid-state hole conductor (SSHC), i.e., the Spiro-OMeTAD [2,2 ‘,7,7 ‘-tetrakis (N,N-di-p-methoxyphenyl-amine) 9,9 ‘-spirobifluorene], and…

Understanding segregation processes in SAMs formed by mixtures of hydroxylated and non-hydroxylated fatty acids

In this paper, we focus on the segregation processes emerging when preparing mixtures with different compositions of aleuritic (9,10,16 trihydroxyhexadecanoic) (ALE) and palmitic (hexadecanoic) (PAL) acids. The combination of atomic force microscopy (AFM) and molecular dynamics (MD) simulations enabled us to prove the role of the functional groups in the formation of self-assembled monolayers (SAMs)…

Low temperature synthesis of an equiatomic (TiZrHfVNb)C5 high entropy carbide by a mechanically-induced carbon diffusion route

A novel, homogeneous, nanostructured and equiatomic (TiZrHfVNb)C-5 High Entropy Carbide (HEC) was successfully synthesised in a powder form by a mechanosynthesis process from the elemental mixture. This synthesis method for HECs, not previously reported, is simple, reproducible and carried out at room temperature. During milling, the transition metals (Ti, Zr, Hf, V and Nb) alloying…

Graphene Formation Mechanism by the Electrochemical Promotion of a Ni Catalyst

In this work, we show that multilayer graphene forms by methanol decomposition at 280 degrees C on an electrochemically promoted nickel catalyst film supported on a K-beta Al2O3 solid electrolyte. In operando near ambient pressure photoemission spectroscopy and electrochemical measurements have shown that polarizing negatively the Ni electrode induces the electrochemical reduction and migration of…

3D Organic Nanofabrics: Plasma-Assisted Synthesis and Antifreezing Behavior of Superhydrophobic and Lubricant-Infused Slippery Surfaces

Herein, we present the development of supported organic nanofabrics formed by a conformal polymer-like interconnection of small-molecule organic nanowires and nanotrees. These organic nanostructures are fabricated by a combination of vacuum and plasma-assisted deposition techniques to generate step by step, single-crystalline organic nanowires forming one-dimensional building blocks, organic nanotrees applied as three-dimensional templates, and the…

Hydrophobic and Icephobic Behaviour of Polyurethane-Based Nanocomposite Coatings

In this paper, hydrophobic nanocomposite coatings based on polyurethane (PUR) modified by nano-silica and silane-based compounds were manufactured by spraying. The main challenge was to assess and improve the hydrophobic as well as anti-icing properties of initially hydrophilic polymer coatings. The prepared nanocomposite coatings were characterized by means of scanning electron microscopy (SEM), optical profilometry…