Exploring the local environment of the engineered nanoclay Mica-4 under hydrothermal conditions using Eu(3+)as a luminescent probe

High charge mica Na4Al4Si4Mg6O20F4 , Mica-4, is a promising candidate as a filling material to immobilize high-level radioactive waste in deep geological repositories due to its extraordinary adsorption capacity. In contrast to traditional clay materials, the structural composition of this mica, with a high content of alu-minum in the tetrahedral sheet, enhances its chemical reactivity,…

Insights into the Impact of Activators on the ‘Catalytic’ Graphitization to Design Anode Materials for Lithium Ion Batteries

In this work, we systematically investigate the ‘catalytic’ graphitization of a biomass precursor (coffee ground) using 10-60 wt.% of the activator iron (III) chloride hexahydrate in a temperature range of 1000 degrees C-2400 degrees C. Special focus is put on the correlation of synthesis conditions, e.g., heat treatment temperature and mass fraction of iron chloride,…

Materiales termoquímicos para almacenamiento de energía mejorados mediante control microestructural

El objetivo principal del proyecto MOTHERESE es el desarrollo de un nuevo concepto de almacenamiento termoquímico de energía basado en el proceso de “Calcium-Looping”. La novedad del concepto radica en disminuir la escala del componente de almacenamiento y dotarlo de un carácter modular, fácilmente integrable en plantas de generación de energía de diversa naturaleza, almacenable y…

Greaseproof, hydrophobic, and biodegradable food packaging bioplastics from C6-fluorinated cellulose esters

Tridecafluorononanoic acid (TFNA), a C6-fluorinated carboxylic acid, was esterified with cellulose at different molar ratios (0:1, 1:1, 2:1, and 3:1) in a trifluoroacetic acid (TFA):trifluoroacetic anhydride (TFAA):CHCl3 (2:1:1, v:v:v) solvent mixture. Free-standing films were obtained for all formulations and are presented as alternatives to composites and blends of paper with fluorinated molecules. Mechanical properties were…

Transparent, UV-blocking, and high barrier cellulose-based bioplastics with naringin as active food packaging materials

Free-standing, robust, and transparent bioplastics were obtained by blending cellulose and naringin at different proportions. Optical, thermal, mechanical, antioxidant, and antimicrobial properties were systematically investigated. In general, the incorporation of naringin produced important UV blocking and plasticizer effects and good antioxidant and antibacterial properties. Moreover, the barrier properties were characterized by determination of their water and oxygen transmission rates, finding that both parameters decreased by increasing…

Structural analysis of mixed alpha- and beta-amyrin samples

Little is known about the structure and molecular arrangement of alpha- and beta-amyrin, a class of triterpenoids found within the cuticle of higher plants. Blends of both amyrin isomers with different ratios have been studied taking into consideration a combined methodology of density functional theory (DFT) calculations with experimental data from scanning electron microscopy, differential…

Insight into the role of temperature, time and pH in the effective zirconium retention using clay minerals

The use of zirconium in chemical industries generates a potential risk of Zr contamination in the environment, with particular concern for the decommissioning of uranium-graphite reactors. Among the natural adsorbents employed for the treatment of nuclear waste, clay minerals showed a very high affinity adsorption for radionuclides, but the influence of the chemical composition, pressure,…

Highly Anisotropic Organometal Halide Perovskite Nanowalls Grown by Glancing-Angle Deposition

Polarizers are ubiquitous components in current optoelectronic devices as displays or photographic cameras. Yet, control over light polarization is an unsolved challenge, since the main drawback of the existing display technologies is the significant optical losses. In such a context, organometal halide perovskites (OMHP) can play a decisive role given their flexible synthesis with tunable…