Electrochemical Deposition of Manganese Oxide on Paper-Based Laser-Induced Graphene for the Fabrication of Sustainable High-Energy-Density Supercapacitors

Laser-induced graphene (LIG) is widely used to fabricate microsupercapacitors (MSCs) on various sustainable substrates, such as wood, cork, and lignin. However, the fabrication of MSCs, especially high energy density devices on paper, has rarely been reported. In this work, LIG electrodes are fabricated on wax-coated paper, followed by electrochemical deposition of manganese oxide (MnO2). The…

Revisiting plant cuticle biophysics

The plant cuticle is located at the interface of the plant with the environment, thus acting as a protective barrier against biotic and abiotic external stress factors, and regulating water loss. Additionally, it modulates mechanical stresses derived from internal tissues and also from the environment. Recent advances in the understanding of the hydric, mechanical, thermal,…

Lacas sostenibles, bioactivas, antioxidantes y reforzadas a partir de orujo de tomate para envases metálicos alimentarios

El envasado de alimentos a través de latas de conservas ha demostrado su eficacia a lo largo de los años al mantener las propiedades nutritivas y organolépticas de los alimentos conservados durante largos periodos de tiempo. Los metales utilizados para las latas son típicamente recubiertos con resinas o lacas para evitar su corrosión y el…

Elucidating the Mechanism of Iron-Catalyzed Graphitization: The First Observation of Homogeneous Solid-State Catalysis

Carbon is a critical material for existing and emerging energy applications and there is considerable global effort in generating sustainable carbons. A particularly promising area is iron-catalyzed graphitization, which is the conversion of organic matter to graphitic carbon nanostructures by an iron catalyst. In this paper, it is reported that iron-catalyzed graphitization occurs via a…

A zirconia/tantalum biocermet: in vitro and in vivo evaluation for biomedical implant applications

A biocermet made of zirconia/20 vol% tantalum (3Y-TZP/Ta) is a new composite with exceptional capabilities due to a combination of properties that are rarely achieved in conventional materials (high strength and toughness, cyclic fatigue resistance and flaw tolerance, wear resistance, corrosion resistance, electrical conductivity, etc.). In this study, for the first time, the biomedical performance…

Direct laser writing of MnOx decorated laser-induced graphene on paper for sustainable microsupercapacitor fabrication

Laser-induced graphene (LIG) on paper is a popular choice for fabricating flexible micro-supercapacitors (MSCs) as it is a simple and sustainable process. However, carbon-based MSC electrodes have limited energy densities. To address this challenge, this study presents a highly reproducible and cost-effective method for decorating manganese oxide (MnOx) x ) on interdigital LIG MSC electrodes,…

Transparent, plasticized cellulose-glycerol bioplastics for food packaging applications

Free-standing films have been obtained by drop-casting cellulose-glycerol mixtures (up to 50 wt% glycerol) dissolved in trifluoroacetic acid and trifluoroacetic anhydride (TFA:TFAA, 2:1, v:v). A comprehensive examination of the optical, structural, mechanical, thermal, hydrodynamic, barrier, migration, greaseproof, and biodegradation characteristics of the films was conducted. The resulting cellulose-glycerol blends exhibited an amorphous molecular structure and a…

Materials for 3D Printed Metal and Metal-Ion Batteries

The review provides an overview of the latest innovations, trends, and challenges in the field of 3D-printed metal and metal-ion batteries. It focuses on the materials used in the printing of batteries, including electrodes, electrolytes, and other electroactive components. Compared to other high-quality reviews on the topic, this review provides a broader selection of materials…

Green Fabrication of Stackable Laser-Induced Graphene Micro-Supercapacitors under Ambient Conditions: Toward the Design of Truly Sustainable Technological Platforms

Extensive research into green technologies is driven by the worldwide push for eco-friendly materials and energy solutions. The focus is on synergies that prioritize sustainability and environmental benefits. This study explores the potential of abundant, non-toxic, and sustainable resources such as paper, lignin-enriched paper, and cork for producing laser-induced graphene (LIG) supercapacitor electrodes with improved…

Direct Laser Writing: From Materials Synthesis and Conversion to Electronic Device Processing

Direct Laser Writing (DLW) has been increasingly selected as a microfabrication route for efficient, cost-effective, high-resolution material synthesis and conversion. Concurrently, lasers participate in the patterning and assembly of functional geometries in several fields of application, of which electronics stand out. In this review, recent advances and strategies based on DLW for electronics microfabrication are…