The impact of interfacial quality and nanoscale performance disorder on the stability of alloyed perovskite solar cells

Microscopy provides a proxy for assessing the operation of perovskite solar cells, yet most works in the literature have focused on bare perovskite thin films, missing charge transport and recombination losses present in full devices. Here we demonstrate a multimodal operando microscopy toolkit to measure and spatially correlate nanoscale charge transport losses, recombination losses and…

Better together: Monolithic halide perovskite@metal-organic framework composites

The instability and limited scalability of halide perovskites hinder their long-term viability in applications as X-ray detectors. Here, we introduce a sol-gel ship-in-bottle approach to produce a monolithic perovskite@metal-organic framework (MOF) composite, combining the properties of the individual building blocks and enhancing density, robustness, and stability. By tuning seed particles below 100 nm, we achieve highly crystalline,…

Strong angular and spectral narrowing ofelectroluminescence in an integrated Tamm-plasmon-driven halide perovskite LED

Next-generation light-emitting applications such as displays and opticalcommunications require judicious control over emitted light, includingintensity and angular dispersion. To date, this remains a challenge as con-ventional methods require cumbersome optics. Here, we report highly direc-tional and enhanced electroluminescence from a solution-processed quasi-2-dimensional halide perovskite light-emitting diode by building a devicearchitecture to exploit hybrid plasmonic-photonic Tamm…

Multifold Enhanced Photon Upconversion in a Composite Annihilator System Sensitized by Perovskite Nanocrystals

Photon upconversion via triplet-triplet annihilation (TTA-UC) provides a pathway to overcoming the thermodynamic efficiency limits in single-junction solar cells by allowing the harvesting of sub-bandgap photons. Here, we use mixed halide perovskite nanocrystals (CsPbX3, X = Br/I) as triplet sensitizers, with excitation transfer to 9,10-diphenylanthracene (DPA) and/or 9,10-bis[(triisopropylsilyl)ethynyl]anthracene (TIPS-An) which act as the triplet annihilators.…

Synergetic Near- and Far-Field Plasmonic Effects for Optimal All-Perovskite Tandem Solar Cells with Maximized Infrared Absorption

The efficiency and reliability of perovskite solar cells have rapidly increased in conjunction with the proposition of advanced single-junction and multi-junction designs that allow light harvesting to be maximized. However, Sn-based compositions required for optimized all-perovskite tandem devices have reduced absorption coefficients, as opposed to pure Pb perovskites. To overcome this, we investigate near- and…

Detectores de Rayos X basados en Compuestos de Perovskita

Las imágenes médicas obtenidas mediante tomografía axial computarizada (TAC) podrían volverse mucho más precisas gracias a los detectores de conteo de fotones. Sin embargo, los materiales que se emplean actualmente para fabricar estos detectores, basados en el cadmio, requieren una pureza extremadamente difícil, y por tanto económicamente costosa de conseguir. El proyecto de Miguel Anaya…

Perovskitas de haluro libres de ligando en GaN poroso para aplicaciones de emisión de luz de nueva generación

PEROGAN propone un material disruptivo mediante el crecimiento de emisores de perovskita de haluro dentro de los poros de GaN nanoestructurado. El proyecto estará impulsado por el modelado óptico y la visualización de las propiedades del material donde la interacción entre la fotofísica, la composición y la estructura se controlará a nanoescala. Perovskitas de haluro…

Understanding ice and water film formation on soil particles by combining density functional theory and Casimir-Lifshitz forces

Thin films of ice and water on soil particles play crucial roles in environmental and technological processes. Understanding the fundamental physical mechanisms underlying their formation is essential for advancing scientific knowledge and engineering practices. Herein, we focus on the role of the Casimir-Lifshitz force, also referred to as dispersion force, in the formation and behavior…

Surfactant-Dependent Bulk Scale Mechanochemical Synthesis of CsPbBr3 Nanocrystals for Plastic Scintillator-Based X-ray Imaging

We report a facile, solvent-free surfactant-dependentmechanochemicalsynthesis of highly luminescent CsPbBr3 nanocrystals (NCs)and study their scintillation properties. A small amount of surfactantoleylamine (OAM) plays an important role in the two-step ball millingmethod to control the size and emission properties of the NCs. Thesolid-state synthesized perovskite NCs exhibit a high photoluminescencequantum yield (PLQY) of up to 88%…

Non-sticky interactions

Quantum mechanical fluctuations of the electromagnetic field in a vacuum between two close together objects result in an attractive force. Now, it has been experimentally shown that by exploiting a similar repulsive interaction, attraction between objects can be modulated simply by tuning temperature.