Unveiling the Potential of a Cobalt-Based Metal-Organic Framework in Carbodiimide Synthesis

The synthesis of carbodiimides via nitrene transfer to isocyanides has garnered significant attention in recent years. However, this reaction predominantly relies on homogeneous catalytic systems with high catalyst loadings. In this study, we employed ZIF-67 MOF as a heterogeneous catalyst for carbodiimide synthesis and conducted an in-depth analysis of its stability. Our findings reveal the…