Low-Temperature Remote Plasma Synthesis of Highly Porous TiO2 as Electron Transport Layers in Perovskite Solar Cells

Halide perovskite solar cells (PSCs) offer high efficiency at low production costs, making them a promising solution for future photovoltaic technologies. Optimizing charge transport layers is crucial, with porous TiO2 widely used as electron transport layers (ETLs) due to their suitable energy band alignment, transparency, and abundance. However, their performance depends strongly on crystallinity, requiring…

Environmentally Tight TiO2-SiO2 Porous 1D-Photonic Structures

Although thin film porosity is the basis of many optical sensors, it can be deleterious for a stable optical behavior of passive optical elements due to the condensation of water and other vapors in their pores. This paper proposes a new strategy for the magnetron sputtering (MS) fabrication of environmentally tight SiO2-TiO2 porous multilayers. Thin…

The Role of Surface Recombination on the Performance of Perovskite Solar Cells: Effect of Morphology and Crystalline Phase of TiO2 Contact

Herein, the preparation of 1D TiO2 nanocolumnar films grown by plasma-enhanced chemical vapor deposition is reported as the electron selective layer (ESL) for perovskite solar devices. The impact of the ESL architecture (1D and 3D morphologies) and the nanocrystalline phase (anatase and amorphous) is analyzed. For anatase structures, similar power conversion efficiencies are achieved using…

Low-Temperature Plasma Processing of Platinum Porphyrins for the Development of Metal Nanostructured Layers

This article establishes the bases for a vacuum and plasma supported methodology for the fabrication at mild temperatures of nanostructured platinum in the form of porous layers and nanocolumns using platinum octaethylporphyrin as precursor. In addition, the application of these materials as tunable optical filters and nano-counterelectrodes is proved. On one hand, the transparency in…

Nanometer-Scale Precision Tuning of 3D Photonic Crystals Made Possible Using Polyelectrolytes with Controlled Short Chain Length and Narrow Polydispersity

Nanometer-scale tuning of the optical properties of prefabricated photonic crystals is achieved via layer-by-layer assembly of polyelectrolytes in the interstitial spaces of the photonic lattice. The key to the approach is using polyelectrolytes with controlled short chain lengths. This ensures they do not block the air voids, thereby maintaining uniform coating and thus precise and reproducible…