{"id":29532,"date":"2008-06-30T23:43:29","date_gmt":"2008-06-30T21:43:29","guid":{"rendered":"https:\/\/icmsva.vallealto.es\/?articulos_sci=degradation-of-phenylmercury-compounds-by-heterogeneous-photocatalysis-over-alpha-fe2o3"},"modified":"2008-06-30T23:43:29","modified_gmt":"2008-06-30T21:43:29","slug":"degradation-of-phenylmercury-compounds-by-heterogeneous-photocatalysis-over-alpha-fe2o3","status":"publish","type":"articulos_sci","link":"https:\/\/icmsva.vallealto.es\/?articulos_sci=degradation-of-phenylmercury-compounds-by-heterogeneous-photocatalysis-over-alpha-fe2o3","title":{"rendered":"Degradation of phenylmercury compounds by heterogeneous photocatalysis over alpha-Fe2O3"},"content":{"rendered":"<p>We report here on the\u00a0degradation\u00a0of\u00a0diphenylmercury and monophenylmercury chloride in air-equilibrated aqueous solutions\u00a0by\u00a0heterogeneous\u00a0photocatalysis\u00a0over\u00a0alpha-Fe2O3.\u00a0Photocatalysis\u00a0proceeded via sequential de-phenylation leaving inorganic mercury. GC-MS analysis\u00a0of\u00a0the products revealed that photocatalytic\u00a0degradation\u00a0involved hydroxylation\u00a0of\u00a0the phenyl rings. Mechanistic features and photocatalytic activity were also studied and are reported upon.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>We report here on the\u00a0degradation\u00a0of\u00a0diphenylmercury and monophenylmercury chloride in air-equilibrated aqueous solutions\u00a0by\u00a0heterogeneous\u00a0photocatalysis\u00a0over\u00a0alpha-Fe2O3.\u00a0Photocatalysis\u00a0proceeded via sequential de-phenylation leaving inorganic mercury. GC-MS analysis\u00a0of\u00a0the products revealed that photocatalytic\u00a0degradation\u00a0involved hydroxylation\u00a0of\u00a0the phenyl rings. Mechanistic features and photocatalytic activity were also studied and are reported upon.<\/p>\n","protected":false},"featured_media":0,"template":"","autores":[],"grupos_de_investigacion":[135],"revistas":[5102],"anos":[897],"class_list":["post-29532","articulos_sci","type-articulos_sci","status-publish","hentry","grupos_de_investigacion-fotocatalisis-heterogenea-aplicaciones","revistas-journal-of-advanced-oxidation-technologies","anos-897","description-off"],"acf":[],"_links":{"self":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/29532","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci"}],"about":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/types\/articulos_sci"}],"version-history":[{"count":0,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/29532\/revisions"}],"wp:attachment":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=29532"}],"wp:term":[{"taxonomy":"autores","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fautores&post=29532"},{"taxonomy":"grupos_de_investigacion","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fgrupos_de_investigacion&post=29532"},{"taxonomy":"revistas","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Frevistas&post=29532"},{"taxonomy":"anos","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fanos&post=29532"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}