{"id":28629,"date":"2011-07-31T23:40:15","date_gmt":"2011-07-31T21:40:15","guid":{"rendered":"https:\/\/icmsva.vallealto.es\/?articulos_sci=mechanochemical-synthesis-of-ti1%e2%88%92xzrxb2-and-ti1%e2%88%92xhfxb2-solid-solutions"},"modified":"2026-04-14T11:49:36","modified_gmt":"2026-04-14T09:49:36","slug":"mechanochemical-synthesis-of-ti1%e2%88%92xzrxb2-and-ti1%e2%88%92xhfxb2-solid-solutions","status":"publish","type":"articulos_sci","link":"https:\/\/icmsva.vallealto.es\/?articulos_sci=mechanochemical-synthesis-of-ti1%e2%88%92xzrxb2-and-ti1%e2%88%92xhfxb2-solid-solutions","title":{"rendered":"Mechanochemical synthesis of Ti1\u2212xZrxB2 and Ti1\u2212xHfxB2 solid solutions"},"content":{"rendered":"<figure><img decoding=\"async\" src=\"https:\/\/icmsva.vallealto.es\/wp-content\/uploads\/2011\/07\/Mechanochemical-synthesis-of-Ti1\u2212xZrxB2-and-Ti1\u2212xH-1.png\" alt=\"Mechanochemical synthesis of Ti1\u2212xZrxB2 and Ti1\u2212xHfxB2 solid solutions\" \/><\/figure>\n<p>Solid solutions of TiB2-ZrB2 and TiB 2-HfB2 were obtained under an inert atmosphere by high-energy ball-milling mixtures of Ti\/Zr\/B and Ti\/Hf\/B, respectively. Milling promoted mechanically induced self-sustaining reactions (MSR), and the ignition time was dependent on the initial composition of the mixture. The stoichiometry of Ti1-xZrxB2 and Ti1-xHf xB2 solid solutions was controlled by adjusting the atomic ratio of the reactants. The solid solutions were characterised by X-ray diffraction, transmission electron microscopy, electron diffraction, and energy dispersive X-ray spectroscopy. The results revealed that TiB2- ZrB2 possessed a nanometric microstructure and good chemical homogeneity. However, in the TiB2-HfB2 system, an inhomogeneous solid solution was obtained when a Ti-rich mixture was employed. The solid solutions showed good thermal stability; thus, can be used as raw materials for the development of technological materials for structural applications.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Solid solutions of TiB2-ZrB2 and TiB 2-HfB2 were obtained under an inert atmosphere by high-energy ball-milling mixtures of Ti\/Zr\/B and Ti\/Hf\/B, respectively. Milling promoted mechanically induced self-sustaining reactions (MSR), and the ignition time was dependent on the initial composition of the mixture. The stoichiometry of Ti1-xZrxB2 and Ti1-xHf xB2 solid solutions was controlled by adjusting&hellip;<\/p>\n","protected":false},"featured_media":28636,"template":"","autores":[],"grupos_de_investigacion":[139],"revistas":[239],"anos":[894],"destacados":[],"class_list":["post-28629","articulos_sci","type-articulos_sci","status-publish","has-post-thumbnail","hentry","grupos_de_investigacion-reactividad-de-solidos","revistas-ceramics-international","anos-894","description-off"],"acf":[],"_links":{"self":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/28629","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci"}],"about":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/types\/articulos_sci"}],"version-history":[{"count":1,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/28629\/revisions"}],"predecessor-version":[{"id":28637,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/28629\/revisions\/28637"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/media\/28636"}],"wp:attachment":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=28629"}],"wp:term":[{"taxonomy":"autores","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fautores&post=28629"},{"taxonomy":"grupos_de_investigacion","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fgrupos_de_investigacion&post=28629"},{"taxonomy":"revistas","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Frevistas&post=28629"},{"taxonomy":"anos","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fanos&post=28629"},{"taxonomy":"destacados","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fdestacados&post=28629"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}