{"id":25359,"date":"2020-01-31T23:50:08","date_gmt":"2020-01-31T22:50:08","guid":{"rendered":"https:\/\/icmsva.vallealto.es\/?articulos_sci=synthesis-of-mn2-doped-zns-by-a-mechanically-induced-self-sustaining-reaction"},"modified":"2026-04-14T11:44:49","modified_gmt":"2026-04-14T09:44:49","slug":"synthesis-of-mn2-doped-zns-by-a-mechanically-induced-self-sustaining-reaction","status":"publish","type":"articulos_sci","link":"https:\/\/icmsva.vallealto.es\/?articulos_sci=synthesis-of-mn2-doped-zns-by-a-mechanically-induced-self-sustaining-reaction","title":{"rendered":"Synthesis of Mn2+-doped ZnS by a mechanically induced self-sustaining reaction"},"content":{"rendered":"<figure><img decoding=\"async\" src=\"https:\/\/icmsva.vallealto.es\/wp-content\/uploads\/2020\/01\/Synthesis-of-Mn2-doped-ZnS-by-a-mechanically-indu-1.png\" alt=\"Synthesis of Mn2+-doped ZnS by a mechanically induced self-sustaining reaction\" \/><\/figure>\n<p>The mechanochemical process denoted as a mechanically induced self-sustaining reaction was successfully applied in obtaining Mn-doped ZnS samples with Mn content between 0 and 5 mol%. The process consists in milling Zn\/Mn\/S powder elemental mixtures with the appropriate stoichiometry, which promotes after approximately 80 min the induction of a combustion reaction. The doping level was properly adjusted by controlling the atomic ratio of the starting mixture. A complete characterization of samples was carried out, including X-ray diffraction, high-resolution transmission electron microscopy, selected area electron diffraction, energy-dispersive X-ray spectroscopy, Raman spectroscopy, diffuse reflectance UV-Vis spectroscopy and emission and excitation photoluminescence measurements. A wurtzite structure, in which Mn2+ replaces Zn2+, was obtained with a nanometric character. The photoluminescence of samples showed the characteristic (Mn2+T1)-T-4-(6)A(1) emission that was highly dependent on the doping level. The maximum luminescence efficiency through the ZnS excitation was found for a doping value of 1 mol%. The photoluminescence showed virtually no contribution from the host emission, which confirmed that samples were properly doped.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>The mechanochemical process denoted as a mechanically induced self-sustaining reaction was successfully applied in obtaining Mn-doped ZnS samples with Mn content between 0 and 5 mol%. The process consists in milling Zn\/Mn\/S powder elemental mixtures with the appropriate stoichiometry, which promotes after approximately 80 min the induction of a combustion reaction. The doping level was&hellip;<\/p>\n","protected":false},"featured_media":25367,"template":"","autores":[],"grupos_de_investigacion":[139],"revistas":[290],"anos":[885],"destacados":[],"class_list":["post-25359","articulos_sci","type-articulos_sci","status-publish","has-post-thumbnail","hentry","grupos_de_investigacion-reactividad-de-solidos","revistas-journal-of-materials-science","anos-885","description-off"],"acf":[],"_links":{"self":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/25359","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci"}],"about":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/types\/articulos_sci"}],"version-history":[{"count":1,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/25359\/revisions"}],"predecessor-version":[{"id":25368,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/articulos_sci\/25359\/revisions\/25368"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=\/wp\/v2\/media\/25367"}],"wp:attachment":[{"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=25359"}],"wp:term":[{"taxonomy":"autores","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fautores&post=25359"},{"taxonomy":"grupos_de_investigacion","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fgrupos_de_investigacion&post=25359"},{"taxonomy":"revistas","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Frevistas&post=25359"},{"taxonomy":"anos","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fanos&post=25359"},{"taxonomy":"destacados","embeddable":true,"href":"https:\/\/icmsva.vallealto.es\/index.php?rest_route=%2Fwp%2Fv2%2Fdestacados&post=25359"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}