
In this work, we demonstrate a synthetic route to attain methylammonium lead bromide (CH3NH3PbBr3) perovskite nanocrystals (nc-MAPbBr(3), 1.5 nm < size < 3 nm) and provide them with functionality as highly efficient flexible, transparent, environmentally stable, and adaptable color converting films. We use nanoparticle metal oxide (MOx) thin films as porous scaffolds of controlled nanopores size distribution to synthesize nc-MAPbBr(3) through the infiltration of perovskite liquid precursors. We find that the control over the reaction volume imposed by the nanoporous scaffold gives rise to a strict control of the nanocrystal size, which allows us to observe well-defined quantum confinement effects on the photo-emission, being the luminescence maximum tunable with precision between lambda = 530 nm (green) and lambda = 490 nm (blue). This hybrid nc-MAPbBr(3)/MOx structure presents high mechanical stability and permits subsequent infiltration with an elastomer to achieve a self-standing flexible film, which not only maintains the photo-emission efficiency of the nc-MAPbBr(3) unaltered but also prevents their environmental degradation. Applications as adaptable color-converting layers for light-emitting devices are envisaged and demonstrated.

