HfB2 ceramic polycrystals: A low-temperature metal-like ceramic at high temperatures?

Scripta Materialia, 203 (2021) 114037

HfB2 ceramic polycrystals: A low-temperature metal-like ceramic at high temperatures?

Hafnium diboride (HfB2) is a highly refractory (melting above 3000 degrees C) ceramic with many potential applications at high temperatures. To enable its use at temperature for extended periods its high-temperature plasticity must be known. This paper examines the mechanical response at temperatures between 900 degrees C and 2000 degrees C in air and in a reducing atmosphere, interpreting the data in the frame of classical models for the plasticity of compact-packed metals at low temperatures. In particular, the Friedel law and the principle of similitude for dislocation patterning are assessed. This reveals that HfB2 is a singular example of a ceramic material with «metal» mechanical behaviour.

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