Grain-boundary diffusion coefficient in alpha-Al2O3 from spark plasma sintering tests: Evidence of collective motion of charge disconnections

Ceramics International, 44 (2018) 19044-19048

Grain-boundary diffusion coefficient in alpha-Al2O3 from spark plasma sintering tests: Evidence of collective motion of charge disconnections

The sintering of fine-grained a-alumina by spark plasma sintering (SPS) was performed to study grain growth under SPS conditions. Grain growth is found to be extensive at relative densities above 95%. A grain growth versus dwell time analysis during SPS allows for the determination of the grain-boundary diffusion coefficient. This study shows that the remarkable enhancement of grain-boundary diffusion derived from a previous analysis could be a consequence of the presence of the recently discovered «disconnections» at the grain boundaries of alpha-alumina. Their presence, together with their electric charge and the external electric field at the boundaries, are the key ingredients for a violation of the typical grain growth kinetic law. When they are introduced appropriately, an updated value of the grain-boundary diffusion coefficient is achieved. A comparison with other values reported previously in the literature through other techniques and a critical analysis are also carried out.

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