Tuning the transmittance and the electrochromic behavior of CoxSiyOz thin films prepared by magnetron sputtering at glancing angle

Solar Energy Materials and Solar Cells, 123 (2014) 130-138

Tuning the transmittance and the electrochromic behavior of CoxSiyOz thin films prepared by magnetron sputtering at glancing angle

This work reports the synthesis and the characterization of amorphous CoxSiyOz thin films prepared by magnetron sputtering from a single cathode. Porous layers with outstanding electrochromic properties are obtained at room temperature in one step by performing the deposition at a glancing angle configuration. The electrochromic behavior of these layers in a basic aqueous medium was dependent on the Co/Si ratio in the films and in all cases was characterized by a fast response, a high coloration efficiency and a complete reversibility after several hundred cycles. A characteristic feature of these electrochromic layers is that, for a similar thickness, the range of transmittance modulation can be tuned by changing the Co/Si ratio in the films and, specifically for films with a high concentration of silicon, to change their aspect from an almost transparent to a full colored state.

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